Here is a list of various samples and articles for making use of DirectXTK.
http://code.msdn.microsoft.com/DirectXTK-Simple-Sample-608bc274
Simple Sample for Windows 8.1
http://code.msdn.microsoft.com/DirectXTK-Simple-Sample-a0b6de36
DirectX Tool Kit – native “XNA” for Windows 8
http://www.tonicodes.net/blog/directx-tool-kit-native-xna-for-windows-8/
Windows Store DirectX C++ Sample Base
http://geekswithblogs.net/mikebmcl/archive/2013/01/31/windows-store-directx-c-sample-base.aspx
http://code.msdn.microsoft.com/DirectXTK-Simple-Win32-23db418a
Simple Sample (Windows 8.x)
http://code.msdn.microsoft.com/DirectXTK-for-Audio-Simple-9d6a7da2
Simple Sample (DirectX SDK)
http://code.msdn.microsoft.com/DirectXTK-for-Audio-Simple-928e0700
DXUT+DirectXTK Simple Sample
http://code.msdn.microsoft.com/DXUTDirectXTK-Simple-Win32-9cf797e9
http://code.msdn.microsoft.com/DirectXTK-Simple-Windows-80e6b591
Marble Maze sample for Windows Phone 8
http://code.msdn.microsoft.com/Marble-Maze-sample-for-c9f3706b
Direct3D with XAML Marble Maze
http://code.msdn.microsoft.com/Direct3D-with-XAML-Marble-1d51a37b
Getting Started with Direct3D on Windows Phone 8
http://www.catalinzima.com/2012/11/getting-started-with-direct3d-on-windows-phone-8-for-2d-game-development/
DirectX on Windows Phone: 2D Game Example using DirectX Toolkit
http://www.developer.nokia.com/Community/Wiki/DirectX_on_Windows_Phone:_2D_Game_Example_using_DirectX_Toolkit
Windows Store apps
Simple Sample for Windows 8http://code.msdn.microsoft.com/DirectXTK-Simple-Sample-608bc274
Simple Sample for Windows 8.1
http://code.msdn.microsoft.com/DirectXTK-Simple-Sample-a0b6de36
DirectX Tool Kit – native “XNA” for Windows 8
http://www.tonicodes.net/blog/directx-tool-kit-native-xna-for-windows-8/
Windows Store DirectX C++ Sample Base
http://geekswithblogs.net/mikebmcl/archive/2013/01/31/windows-store-directx-c-sample-base.aspx
Win32 desktop apps
Simple Sample (no audio)http://code.msdn.microsoft.com/DirectXTK-Simple-Win32-23db418a
Simple Sample (Windows 8.x)
http://code.msdn.microsoft.com/DirectXTK-for-Audio-Simple-9d6a7da2
Simple Sample (DirectX SDK)
http://code.msdn.microsoft.com/DirectXTK-for-Audio-Simple-928e0700
DXUT+DirectXTK Simple Sample
http://code.msdn.microsoft.com/DXUTDirectXTK-Simple-Win32-9cf797e9
Windows phone 8
Simple Samplehttp://code.msdn.microsoft.com/DirectXTK-Simple-Windows-80e6b591
Marble Maze sample for Windows Phone 8
http://code.msdn.microsoft.com/Marble-Maze-sample-for-c9f3706b
Direct3D with XAML Marble Maze
http://code.msdn.microsoft.com/Direct3D-with-XAML-Marble-1d51a37b
Getting Started with Direct3D on Windows Phone 8
http://www.catalinzima.com/2012/11/getting-started-with-direct3d-on-windows-phone-8-for-2d-game-development/
DirectX on Windows Phone: 2D Game Example using DirectX Toolkit
http://www.developer.nokia.com/Community/Wiki/DirectX_on_Windows_Phone:_2D_Game_Example_using_DirectX_Toolkit